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What Is Internal Resistance in Batteries? How It Impacts Efficiency, Performance, and Lifetime

Internal resistance in batteries affecting efficiency, performance, and lifetime.

Battery performance is determined by many factors, but Internal Resistance (IR) is one of the most critical and least understood.
For Energy Storage Systems (ESS), IR directly affects efficiency, available power, heat generation, cycle life, and the system’s long-term economic value.

Understanding how IR works—and how it changes over time—is essential for designing, operating, and maintaining a high-performance and safe ESS.

What Is Internal Resistance?

Internal Resistance is the inherent opposition inside a battery that resists the flow of current.

It has two major components:

(1) Ohmic Resistance

  • From current collectors, electrolyte, separators, and connectors

  • Causes instant voltage drop (IR drop) during charge/discharge

(2) Polarization Resistance

  • From electrochemical reactions

  • Includes:

    • Charge-transfer resistance

    • Diffusion resistance

    • SEI (Solid Electrolyte Interphase) resistance

Total IR = Ohmic Resistance + Polarization Resistance

When current flows through the battery, internal resistance converts some electrical energy into heat:

Heat = I² × R

This is why high IR leads to more heat, lower efficiency, and faster aging.

How Internal Resistance Affects ESS Performance

(1) Lower Efficiency (More Losses)

Higher IR means more electrical energy is lost as heat.

For ESS operation, this results in:

  • Lower Round-Trip Efficiency (RTE)

  • More energy wasted during charge/discharge

  • Higher long-term operational cost

(2) Reduced Power Output

High IR leads to:

  • Increased voltage drop

  • Reduced usable voltage

  • Restricted charge/discharge current

This forces PCS and BMS to limit power to prevent overheating.
The result: the ESS cannot deliver its rated power when IR becomes too high.

(3) Increased Heat and Safety Risks

High IR → Higher heat → Faster aging → Even higher IR

This positive feedback loop can lead to:

  • Accelerated SEI growth

  • Lithium plating at low temperatures

  • Increased risk of thermal incidents

This is why IR is a key parameter monitored by modern BMS.

(4) Shorter Cycle Life

As IR increases:

  • Capacity decreases

  • Power capability drops

  • Cell inconsistency worsens

The system ages faster and becomes less dependable.

What Causes Internal Resistance to Increase?

(1) Natural Aging

Electrode changes and SEI growth are unavoidable.

(2) High Temperature

Chemical aging nearly doubles for every 10°C rise.

(3) High C-rate Charging/Discharging

Accelerates polarization resistance and heat generation.

(4) Low Temperature Operation

Causes lithium plating, which sharply increases IR.

(5) Cell Inconsistency

Weak cells force pack-level derating.

(6) Poor Thermal Management

Hot spots create uneven IR growth and imbalance.

How BMS and AI Monitor Internal Resistance

Modern ESS platforms continuously track IR to ensure safety and performance.

Common measurement methods:

  • DCIR (Direct Current Internal Resistance)

  • ACIR (Alternating Current Internal Resistance)

  • Pulse current testing

  • Machine learning models for SOH estimation

AI-enabled cloud EMS can:

  • Detect abnormal IR increase early

  • Predict future degradation

  • Trigger maintenance warnings

  • Extend system lifetime and protect ROI

How to Maintain Low Internal Resistance

For ESS Operators

  • Maintain 20–35°C operating temperature

  • Avoid unnecessary high C-rate cycles

  • Avoid charging below 0°C

  • Use high-quality LFP cells

  • Keep SOC in a moderate range (10–90%)

  • Ensure proper EMS/PCS tuning

For System Designers

  • Liquid cooling for temperature uniformity

  • High-quality busbars and connectors

  • Advanced BMS for precise balancing

  • AI-based strategies to optimize cycling

Conclusion

Internal resistance is a fundamental metric that determines the efficiency, safety, and lifetime of any energy storage system.

Low IR provides:

  • Higher power output

  • Higher energy efficiency

  • Lower heat generation

  • Longer cycle life

  • Improved economic returns

Monitoring and controlling IR is essential for achieving safe, reliable, and high-value ESS operation—especially as global energy storage deployment accelerates.

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